Project number: 2022-019
Project Status:
Current
Budget expenditure: $191,642.00
Principal Investigator: Christine C. Huynh
Organisation: Nautilus Collaboration Pty Ltd
Project start/end date: 15 Sep 2022 - 29 Jun 2023
Contact:
FRDC

Need

The reduction of total nitrogenous output remains a significant challenge in the pond culture of prawns. The majority of total nitrogen (TN) output from the Australian prawn industry is organic nitrogen, of which microalgae assimilate a large proportion. In response to the industry’s need to remove or reduce microalgae and TN from large quantities of release water, our team proposes a project that would investigate the use of electro-coagulation (EC) technology to remove microalgae and TN from settlement pond discharge. EC is a highly effective electrochemical approach to wastewater treatment, and has been successfully used to assist in the removal of both organic and inorganic contaminants from wastewater (Moussa et al., 2017). This technology works by applying an electrical current through the water, destabilizing/neutralizing the repulsive forces that keep particles suspended, causing these particles to form larger particles that settle for easier separation from water. This method of coagulation has a significant advantage over chemical coagulation/flocculation: coagulants are formed in-situ by electrolytic oxidation of an anode, and therefore additional chemicals, metal salts or polyelectrolytes do not need to be added to the system. This results in less sludge generation as a bi-product of the filtration process (Moussa et al., 2017). NaturalShrimp has spent many years developing, patenting, and commercializing the EC technology for use specifically for aquaculture that not only helps with coagulation but also removes pathogens and ammonia.
The proposed project will be undertaken by Nautilus Collaboration (primary investigators: C van Rijn and C Huynh), Natural Aquatic Solutions (technology supplier – Rep: Tom Untermeyer) and Fresh By Design (installation and maintenance – Lachlan Bassett). The proprietary EC technology developed by Natural Aquatic Solutions has the capacity to treat around 20.5 m3/hr of water. The electrical current passing between the plates removes chlorine from the saltwater as it passes between the plates. The chlorine then combines with the ammonia to form chloramine which is then removed by a carbon filter downstream from the EC. The current is manually adjusted as the ammonia changes to effectively remove the ammonia in one pass through the EC. The ammonia removed by the EC prevents it from further converting to nitrite or nitrate. This controls the level of bacteria, removes ammonia, greatly reduces nitrate output and produces an anti-oxidative water chemistry beneficial to the health of the receiving ecosystem (T Untermeyer, pers. comm.).

Objectives

1. Assess technical feasibility of electrocoagulation unit for wastewater remediation. To achieve this objective the project will collect comprehensive data on relevant water quality and other parameters (i.e., salinity, pH, organic/inorganic particle load, microalgae composition, microalgae concentration, ammonia, chloramine, TKN, total P, TSS, turbidity, free chlorine, total chlorine, bacterial colony counts, thermotolerant coliforms, vibrio sp.) in prawn farm discharge water before and after EC treatment over the production cycle encompassed by this project.
2. Assess the economic feasibility of electrocoagulation for wastewater treatment. To achieve this the project will collect data to determine costs of the EC system including capital and installation costs, daily volume of water treated, daily power consumption, and ongoing maintenance requirements.
3. Determine any bottlenecks for application for prawn effluent treatment. To inform future consideration of subsequent particle removal treatment options that are not part of this project, particle aggregates (density/size) will be characterised over time post EC treatment, including settlement or flotation velocity, and cohesiveness under mechanical stress.

Final report

ISBN: 978-0-646-89042-5
Authors: Christine Huynh Christian van Rijn Tony Land
Final Report • 2024-05-31 • 11.48 MB
2022-019-DLD.pdf

Summary

This project focused on addressing a key challenge of the Australian prawn industry: the reduction/removal of nitrogen (N) and the coagulation of suspended solids (including microalgae) to facilitate the  expansion of the industry whilst continuing to meet these sustainability targets. The project investigated the use of electrocoagulation (EC) as a technology for treatment of water dischaged from an Australian prawn farm. EC technology involves releasing metal-hydroxide cations and producing hydrogen anions by applying a direct electrical current to an electrolytic cell. Most colloidal particles have a negative surface charge and repel each other, but adding positively charged metal-hydroxides destabilises their surface charge and causes them to clump together via van der Waals force. These clumped particles can be removed through sedimentation, flotation, or filtration. Flocculated particles float to the surface with hydrogen gas formation, while compounds bound with metal-hydroxides precipitate out and form sludge.
 
The aims and objectives for the project were to:
1. Assess technical feasibility for commercial application of EC for  wastewater remediation. 
2. Assess the economic feasibility for commercial application of EC for  wastewater treatment.
3. Determine any bottlenecks for commercial application of EC for prawn effluent treatment.
 
A gravity-fed EC unit was installed pondside that drew water from the settlement pond, treated it and then discharged into a settlement tank before spilling over a weir and back into the pond. The five anode/cathode plate  material combinations tested were:
• Mild steel
• Aluminium
• Graphite 
• Titanium-Coated Mixed Metal Oxide 
• Titanium and graphite (using Titanium as power plates)
 
Each electrode plate material was evaluated to determine which was the most effective for this application. Water quality properties of input and output water was monitored during the testing of different plate materials, including nutrients, physicochemical properties, total and soluble metals,and particulate analysis. Operating parameter data was also collected to conduct a feasibility study, including capital and ongoing operating costs for adopting the technology at a commercial scale.

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